Faculty
Joost J. Vlassak
Abbott and James Lawrence Professor of Materials Engineering
Area Dean for Materials Science & Mechanical Engineering

Contact Information
| Office: | 308 Pierce Hall |
| Email: | vlassak@seas.harvard.edu |
| Office Phone: | (617) 496-0424 |
| Office Fax: | (617) 496-0601 |
| Lab Phone: | (617) 496-8145 |
Websites
http://vlassakgroup.seas.harvard.edu
Education
- Burgerlijk Ingenieur, 1989, Metallurgical Engineering, University of Leuven
- M.S., 1990, Materials Science, Stanford University
- Ph.D., 1994, Materials Science, Stanford University
Research Interests
Materials & Devices- Materials Science
- Solid Mechanics
- Surface and Interface Science
Primary Teaching Area
Materials Science & Mechanical Engineering
Profile
The use of thin films in integrated circuits has created a strong interest in the mechanical properties of thin-film materials and materials in small volumes. As the complexity of integrated circuits increases, the materials used in them have to meet more stringent requirements.
Until recently, integrated circuits consisted of relatively few materials: single and polycrystalline silicon, various aluminum alloys, silicon oxides and nitrides of varying composition, as well as barrier films and silicides (TiN, TiSi2, CoSi2, etc.). Recently, however, requirements for better electrical performance have led to the incorporation of a host of new materials such as Cu and dielectrics with low dielectric constants. Integration of these new materials into integrated circuits poses interesting challenges for engineers in research and development organizations.
A good understanding of the mechanical properties of these materials and of the interfaces between them is critical to the successful integration of these materials. Other applications in which mechanical properties of thin films play an important role include micro-electromechanical systems (MEMS), electronic packaging, and data storage (e.g., magnetic storage media).
Professor Vlassak has developed a variety of new experimental techniques for studying the mechanical behavior of thin films. He has investigated the effect of elastic anisotropy on stiffness measurements on small volumes of materials using low-load indentation techniques and has developed a technique for visualizing the plastic displacement field around indentations in multilayered thin films.
He has also developed a method for measuring stress-strain curves of freestanding thin films using silicon micro-machining techniques. His goal is to develop a better understanding of how microstructure controls the mechanical behavior of thin films.
Because adhesion is one of the critical properties that determine the performance of a thin film on a substrate, Professor Vlassak also studies the mechanical behavior of thin-film interfaces. He is currently planning to expand his research to fatigue and fracture toughness of thin films as well as time-dependent properties.
Selected Publications
- P. J. McCluskey, J. J. Vlassak, "Glass transition and crystallization of amorphous Ni-Ti-Zr thin films by combinatorial nano-calorimetry", Scripta Materialia 64(073517), 264-267 (2011). (Download)
- K. Zhao, M. Pharr, J. J. Vlassak, Z. Suo, "Inelastic hosts as electrodes for high-capacity lithium-ion batteries", Journal of Applied Physics 109, 016110 (2011). (Download)
- K. Zhao, M. Pharr, J. J. Vlassak, Z. Suo, "Fracture of electrodes in lithium-ion batteries caused by fast charging", Journal of Applied Physics 108, 073517 (2010). (Download)
- H. Li, J. M. Knaup, E. Kaxiras, J. J. Vlassak, "Stiffening of organosilicate glasses by organic cross-linking", Acta Materialia 59, 44-52 (2011). (Download)
- P. J. McCluskey, J. J. Vlassak, "Combinatorial nanocalorimetry", Journal of Materials Research 25(11), 2086-2100 (2010). (Download)
- P. J. McCluskey, J. J. Vlassak, "Nano-thermal transport array: an instrument for combinatorial measurements of heat transfer in nanoscale films", Thin Solid Films (2010), doi: 10.1016/j.tsf2010.05.124 (Download)
- C. F. Karanikas, H. Li, J. J. Vlassak, J. J. Watkins, "Quantitative interfacial energy measurements of adhesion-promoted thin copper films by supercritical fluid deposition on barrier layers", Journal of Engineering Materials and Technology-Transactions of the ASME 132(2), 021014 (2010). (Download)
- H. Li, N. X. Randall, J. J. Vlassak, "New methods of analyzing indentation experiments on very thin films", Journal of Materials Research 25(4), 728-734 (2010). (Download)
- N. Lu, Z. Suo, J. J. Vlassak, "The effect of film thickness on the failure strain of polymer-supported metal films", Acta Materialia 58, 1679-1687 (2010). (Download)
- Y. Hu, X. Zhao, J. J. Vlassak, Z. Suo, "Using indentation to characterize the poroelasticity of gels", Applied Physics Letters 96, 121904 (2010). (Download)
- Y. Hu, X. Zhao, J. J. Vlassak, Z. Suo, "Using indentation to characterize the poroelasticity of gels", Applied Physics Letters 96, 121904 (2010). (Download)
- Y. Hu, X. Zhao, J. J. Vlassak, Z. Suo, "Using indentation to characterize the poroelasticity of gels", Applied Physics Letters 96, 121904 (2010). (Download)
- X. Wang, J. J. Vlassak, "The effect of film thickness on the martensitic transformation in equi-atomic NiTi thin films constrained by substrates", submitted (2009). (Download)
- H. Li, T. Y. Tsui, J. J. Vlassak, "Water diffusion and fracture behavior in nanoporous low-k dielectric film stacks", J. Appl. Phys. 106, 033503 (2009). (Download)
- Y. Lin, T. Y. Tsui, J. J. Vlassak, "Adhesion degradation and water diffusion in nanoporous organosilicate glass thin film stacks", J. Electrochem. Soc. 157, G53-G56 (2010). (Download)
- N. Lu, X. Wang, Z. Suo, J. J. Vlassak, "Failure by simultaneous grain growth, strain localization, and interface debonding in metal films on polymer substrates", J. Mater. Res. 24(2), 379-385 (2009). (Download)
- H. Li, J. J. Vlassak, "Determining the elastic modulus and hardness of an ultra-thin film on a substrate using nanoindentation", J. Mater. Res. 24(3), (2009). (Download)
